Novel bis-amino acids (Valine and Leucine) and mono-amino acids (Valine and Leucine) fumaramide derivatives have been prepared which contain a vinyl group in the form of a vinyl ester in their structure at the acid end. The newly synthesized derivatives are good supramolecular gelators of organic solvents such as toluene, acetonitrile, o, m, p-xylene and mixtures of water / DMF and water / DMSO. The gelator molecules self-assemble by noncovalent interactions, mainly by hydrogen bonds between the amide group (CONH) and the carboxyl group (COO), thus forming a gel network. Morphology studies show that the gels contain a filamentous structure of nanometer dimensions exhaustive in a three-dimensional network. The prepared derivatives in their structure contain reactive alkyl groups suitable for carrying out the polymerization reaction initiated by gamma or ultraviolet radiation in the supramolecular aggregates of selected gels. It was found that polymerization reactions occur only in the gel network and depend on the structure of the aggregate, ie the proximity and orientation of double bonds in the gel network. Polymers were formed by exposure to gamma and ultraviolet radiation in toluene, acetonitrile and water / DMF gels with transcripts of gel structure into polymers. The polymers formed in the solution do not show the structure of polymer as in the case of gel polymerization. Several instrumental methods have been applied to investigate and characterize supramolecular gels, which include temperature NMR and FTIR spectroscopy, and TEM, SEM, and AFM microscopy have been used to investigate the morphology of gels and polymers.