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doctoral thesis
On the nature of structural fluctuations in complex liquids
Split, Paris: University of Split, University of Split, Faculty of science, 2018. urn:nbn:hr:166:737057
Požar, Martina
University of Split
University of Split, Faculty of science
Department of Physics
France: Sorbonne University
France: École Doctorale Physique en Île-de-France

Cite this document

Požar, M. (2018). On the nature of structural fluctuations in complex liquids (Doctoral thesis). Retrieved from https://urn.nsk.hr/urn:nbn:hr:166:737057

Požar, Martina. "On the nature of structural fluctuations in complex liquids." Doctoral thesis, University of Split, University of Split, Faculty of science; France: Sorbonne University, France: École Doctorale Physique en Île-de-France, 2018. https://urn.nsk.hr/urn:nbn:hr:166:737057

Požar, Martina. "On the nature of structural fluctuations in complex liquids." Doctoral thesis, University of Split, University of Split, Faculty of science; France: Sorbonne University, France: École Doctorale Physique en Île-de-France, 2018. https://urn.nsk.hr/urn:nbn:hr:166:737057

Požar, M. (2018). 'On the nature of structural fluctuations in complex liquids', Doctoral thesis, University of Split, University of Split, Faculty of science; France: Sorbonne University, France: École Doctorale Physique en Île-de-France, accessed 25 January 2021, https://urn.nsk.hr/urn:nbn:hr:166:737057

Požar M. On the nature of structural fluctuations in complex liquids [Doctoral thesis]. Split: University of Split, University of Split, Faculty of science; Paris: France: Sorbonne University, France: École Doctorale Physique en Île-de-France; 2018 [cited 2021 January 25] Available at: https://urn.nsk.hr/urn:nbn:hr:166:737057

M. Požar, "On the nature of structural fluctuations in complex liquids", Doctoral thesis, University of Split, University of Split, Faculty of science, Split; France: Sorbonne University, France: École Doctorale Physique en Île-de-France, Paris, 2018. Available at: https://urn.nsk.hr/urn:nbn:hr:166:737057

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Metadata
TitleOn the nature of structural fluctuations in complex liquids
Title (croatian)O prirodi strukturnih fluktuacija u kompleksnim tekućinama
AuthorMartina Požar
MentorAurélien Perera https://orcid.org/0000-0001-9119-6659 (mentor)
MentorLarisa Zoranić (mentor)
Committee memberJean-François Dufrêche https://orcid.org/0000-0001-8422-3639 (predsjednik povjerenstva)
Committee memberHélène Gerard https://orcid.org/0000-0002-8935-9591 (član povjerenstva)
Committee memberSanja Tomić (član povjerenstva)
Committee memberJadran Vrabec https://orcid.org/0000-0002-7947-4051 (član povjerenstva)
Committee memberLeandra Vranješ Markić (član povjerenstva)
Committee memberDražen Zanchi (član povjerenstva)
GranterUniversity of Split
University of Split, Faculty of science
(Department of Physics)
Split
GranterFrance: Sorbonne University
France: École Doctorale Physique en Île-de-France
Paris
Defense date and country2018-11-16, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Interdisciplinary Natural Sciences
Universal decimal classification
(UDC)		53
NATURAL SCIENCES
Physics
Universal decimal classification
(UDC)		577
NATURAL SCIENCES
Biochemistry. Molecular biology. Biophysics
Abstract
The analysis of different types of structuring, present in simple and complex liquids and their mixtures, was done using the method of molecular dynamics. Complex mixtures have at least one associative component, such as water, alcohols (mono-ols and diols) and amines. The supra-molecular structuring in these mixtures is detected, described, quantified and connected with the atom-atom interactions is the molecules. These systems have interesting fluctuation behaviors, as shown through Kirkwood-Buff integrals. Their correlation functions behave in a complex way, depending on the component, concentration and temperature. The pre-peak at small k values in the site-site structure factor is defined as a signature of molecular domains in these mixtures. A special focus is placed on long-range structuring, which is a novelty considering the majority of the work in the field of the physics of liquids. This thesis contributes to a better understanding of micro-heterogeneous structures in molecular liquids, and gives new links to structural heterogeneities in soft and bio-matter.
Abstract (croatian)
Metodom molekulske dinamike provedena je analiza različitih vrsta uređenja prisutnih u jednostavnim i kompleksnim tekućinama i njihovim binarnim mješavinama. Kompleksne mješavine su one koje imaju barem jednu asocijativnu komponentu, kao što su voda, alkoholi (mono-oli i dioli) i amini. Supra-molekularno strukturiranje u tim mješavinama je detektirano, opisano i kvantificirano, te je povezano s atom-atom interakcijama u molekulama. Pokazano je da ovi sustavi imaju zanimljivo ponašanje fluktuacija, opisano kroz Kirkwood-Buff integrale. Imaju kompleksno ponašanje korelacijskih funkcija ovisno o komponenti, koncentraciji i temperaturi. Signal na malim k vrijednostima atom-atom strukturnih faktora je definiran kao potpis molekularnih domena u tim sistemima. Naročiti naglasak se daje na dugodosežnu organizaciju u mješavinama, što je novost rada u odnosu na većinu literature u polju fizike tekućina. Ova teza doprinosi boljem razumijevanju mikro-heterogene strukture u molekularnim tekućinama, te daje nove poveznice sa strukturnim heterogenostima u mekoj i bio-materiji.
Keywords
Keywords (croatian)
Languageenglish
URN:NBNurn:nbn:hr:166:737057
Study programmeTitle: Postgraduate University Study of Biophysics
Study programme type: university
Study level: postgraduate
Academic / professional title: doktor/doktorica znanosti, područje prirodnih znanosti, polje fizika (doktor/doktorica znanosti, područje prirodnih znanosti, polje fizika)
Type of resourceText
Extent178 str. ; 30 cm
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
RepositoryRepository of Faculty of Science
Created on2019-01-07 12:06:50

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