prikaz prve stranice dokumenta Mechanically flexible crystals of cadmium(II) coordination polymers
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doctoral thesis
Mechanically flexible crystals of cadmium(II) coordination polymers
Zagreb: University of Zagreb, Faculty of Science, 2022. urn:nbn:hr:217:204762
Pisačić, Mateja
University of Zagreb
Faculty of Science
Department of Chemistry

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Pisačić, M. (2022). Mechanically flexible crystals of cadmium(II) coordination polymers (Doctoral thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:204762

Pisačić, Mateja. "Mechanically flexible crystals of cadmium(II) coordination polymers." Doctoral thesis, University of Zagreb, Faculty of Science, 2022. https://urn.nsk.hr/urn:nbn:hr:217:204762

Pisačić, Mateja. "Mechanically flexible crystals of cadmium(II) coordination polymers." Doctoral thesis, University of Zagreb, Faculty of Science, 2022. https://urn.nsk.hr/urn:nbn:hr:217:204762

Pisačić, M. (2022). 'Mechanically flexible crystals of cadmium(II) coordination polymers', Doctoral thesis, University of Zagreb, Faculty of Science, accessed 25 April 2024, https://urn.nsk.hr/urn:nbn:hr:217:204762

Pisačić M. Mechanically flexible crystals of cadmium(II) coordination polymers [Doctoral thesis]. Zagreb: University of Zagreb, Faculty of Science; 2022 [cited 2024 April 25] Available at: https://urn.nsk.hr/urn:nbn:hr:217:204762

M. Pisačić, "Mechanically flexible crystals of cadmium(II) coordination polymers", Doctoral thesis, University of Zagreb, Faculty of Science, Zagreb, 2022. Available at: https://urn.nsk.hr/urn:nbn:hr:217:204762

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Metadata
TitleMechanically flexible crystals of cadmium(II) coordination polymers
Title (croatian)Kristali koordinacijskih polimera kadmija(II) s mehanički potaknutim fleksibilnim odzivom
AuthorMateja Pisačić
MentorMarijana Đaković (mentor)
Committee memberBiserka Prugovečki (predsjednik povjerenstva)
Committee memberDavor Kovačević (član povjerenstva)
Committee memberAna Šantić (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2022-11-24, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Universal decimal classification
(UDC)		54 - Chemistry. Crystallography. Mineralogy
Abstract
Mechanically responsive crystals have recently attracted the attention of a wide scientific community, but the origin of this remarkable crystal behaviour is still unclear. This thesis provides a systematic study of mechanically induced crystal flexibility on a series of onedimensional crystalline cadmium(II) coordination polymers, which provided a valuable dataset of different structural architectures, morphologies, and an unexpectedly wide range of variable mechanical responses. A detailed and systematic correlation of the structural features and mechanical responses using advanced experimental and computational methods, provided a deeper insight into the origin and mechanism of mechanically induced flexibility. It was shown that the relative strength and directionality of intermolecular interactions are one of the key parameters in delivering a specific mechanical response. Thorough research emphasized further importance of the direction-dependent responses, and obtained results provided a fruitful avenue of potential practical applications.
Abstract (croatian)
Iako su u posljednje vrijeme kristali s mehaničkim odzivom privukli znatnu pažnju šire znanstvene zajednice, još uvijek nije jasno koje je strukturno porijeklo ovog izvanrednog ponašanja kristala. U okviru ovog doktorskog rada provedeno je sustavno istraživanje mehanički inducirane fleksibilnosti kristala na nizu jednodimenzijskih koordinacijskih polimera kadmija(II), koji su pružili mnoštvo različitih strukturnih arhitektura, morfologija i neočekivano širok raspon raznovrsnih mehaničkih odgovora. Detaljna i sustavna korelacija strukturnih značajki i mehaničkih odziva, korištenjem naprednih eksperimentalnih i računalnih metoda, omogućila je dublji uvid u podrijetlo i mehanizam mehanički izazvane fleksibilnosti. Utvrđeno je da su relativna jakost i usmjerenost međumolekulskih interakcija jedan od ključnih parametara koji određuju vrstu i stupanj mehaničkog odgovora. Rezultati provedenog istraživanja naglasili su važnost smjera primjene mehaničke sile u ostvarivanju specifičnih odgovora kristala, čime je istaknut širok spektar potencijalne primjene kristala u dizajnu novih, naprednih materijala.
Keywords
Keywords (english)
Languageenglish
URN:NBNurn:nbn:hr:217:204762
Promotion2022
ProjectNumber: IP-2019-04-1242
Title: Od oblika do funkcije: Fleksibilni kristalni materijali s kontroliranim mehaničkim odzivom
Title: From form to function: Mechanically flexible crystalline materials with controllable responses
Acronym: FlexibleCrystals
Leader: Marijana Đaković
Jurisdiction: Croatia
Funder: HRZZ
Funding stream: IP
Study programmeTitle: Doctoral study in chemistry
Study programme type: university
Study level: postgraduate
Academic / professional title: doktor/doktorica znanosti, područje prirodnih znanosti, polje kemija (doktor/doktorica znanosti, područje prirodnih znanosti, polje kemija)
Type of resourceText
ExtentXXXIV, 102 str. ; 30 cm
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
RepositoryRepository of the Faculty of Science
Created on2022-12-08 17:47:26

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